Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries

Wang Qingsheng; Povel Nivokov; Anadoli Popovich; Yu Yao; Yang Zhelong

doi:doi:10.11648/j.ajmsp.20220701.11

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Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries

Wang Qingsheng, Povel Nivokov, Anadoli Popovich, Yu Yao, Yang Zhelong

Published in American Journal of Materials Synthesis and Processing (Volume 7, Issue 1)

Received: 15 December 2021 Accepted: 7 January 2022 Published: 12 January 2022

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Abstract

This article explored the use of atomic layer deposition to deposit cathode material LF(M)S coated with nano-scale Al₂O₃(C) film by growth coating, and successfully obtained the composite LF(M)S coated with Al₂O₃ (C) cathode material. The test results of various electrochemical performance parameters show that the surface modification treatment method can effectively improve the various electrochemical properties of the cathode material. The synthesized LF(M)S was analyzed by a Time of Flight Secondary Ion Mass Spectrometer, and a clear topography and three-dimensional topography of the surface coated with Al₂O₃ and C were obtained; the surface morphology and uniformity of the deposited layer were studied by Atomic Force Microscope and the crystal structure of the material was analyzed by XRD. The electrochemical performance of the battery assembled with the positive electrode material was characterized by an electrochemical workstation and a charge-discharge tester. The results showed that the surface coating can effectively prevent the side reaction between the material and the electrolyte at high voltage, and reduce the irreversible capacity loss in the first charge and discharge process, because the chemical properties of the coating are not active. At the same time, due to the stable structure and good conductivity of the coating material, the stability of the structure during charging and discharging of the material is maintained, thereby reducing the loss of battery capacity, maintaining good conductivity between the material particles, and improving the cycle performance of the material.

Published in	American Journal of Materials Synthesis and Processing (Volume 7, Issue 1)
DOI	10.11648/j.ajmsp.20220701.11
Page(s)	1-7
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Atomic Layer Deposition (ALD), Material Coating Modification, Electrode Passivation, Growth Coating

References

[1]	Makhonina E. V., Meduedeva A. E., Dubasoua V. S., Volkou V. V., Politov Y. A., Eremenko I. L. A new coating for improving the electrochemical performance of cathode materials // International Journal of Hydrogen Energy. ‒ 2016. ‒ T. 41, № 23. ‒ C. 9901-9907.
[2]	Kosova N. V., Devyatkina E. T. Comparative study of LiCoO₂ surface modified with different oxides // Journal of Power Sources. ‒ 2007. ‒ T. 174, № 2. ‒ C. 959964.
[3]	G. S. Higashi and C. G. Fleming, Appl. Phys. Lett., 1989, 55, 1963–1965.
[4]	T. Aaltonen, M. Alnes, O. Nilsen, L. Costelle and H. Fjellvåg, J. Mater. Chem., 2010, 20, 2877–2881.
[5]	Ville Miikkulainen, Ola Nilsen, Mikko Laitinen, b Timo Sajavaarab and Helmer Fjellvag. Atomic layer deposition of LixTiyOz thin films// RSC Advances. – 2013. C. – 7537-7541.
[6]	Popovich, A. A., Maximov, M. Y., Nazarov, D. V., Novikov, P. A., Silin, A. O., Shamshurin, A. I. Low-temperature deposition of tin (IV) oxide films for thin-film power sources. Russian Journal of Applied Chemistry, ‒ 2016. 89 (5), 805–808.
[7]	T. Aaltonen, O. Nilsen, A. Magras and H. Fjellv, Chem. Mater., 2011, 4669–4675.
[8]	X. Li, J. Liu, M. N. Banis, A. Lushington, R. Li, M. Cai and X. Sun, Energy Environ. Sci., 2014, 7, 768–778.
[9]	Jung Y. S., Cavanagh A. S., Dillon A. C., Groner M. D., George S. M., Lee S. H. Enhanced Stability of LiCoO₂ Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition // Journal of the Electrochemical Society. ‒ 2010. ‒ T. 157, № 1. ‒ C. A75-A81.
[10]	Nazarov D. V., Maximov M. Yu., Novikov P. A. Osmolovsky M. G., Rumyantsev A. M. Atomic layer deposition of tin oxide using tetraethyltin to produce high-capacity Li-ion batteries // Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. – 2017. J. Vac. Sci. Technol. A, Vol. 35, No. 1, ‒ C. 01B137-1 – 01B137-11.

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APA Style

Wang Qingsheng, Povel Nivokov, Anadoli Popovich, Yu Yao, Yang Zhelong. (2022). Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. American Journal of Materials Synthesis and Processing, 7(1), 1-7. https://doi.org/10.11648/j.ajmsp.20220701.11

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ACS Style

Wang Qingsheng; Povel Nivokov; Anadoli Popovich; Yu Yao; Yang Zhelong. Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. Am. J. Mater. Synth. Process. 2022, 7(1), 1-7. doi: 10.11648/j.ajmsp.20220701.11

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AMA Style

Wang Qingsheng, Povel Nivokov, Anadoli Popovich, Yu Yao, Yang Zhelong. Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. Am J Mater Synth Process. 2022;7(1):1-7. doi: 10.11648/j.ajmsp.20220701.11

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@article{10.11648/j.ajmsp.20220701.11,
  author = {Wang Qingsheng and Povel Nivokov and Anadoli Popovich and Yu Yao and Yang Zhelong},
  title = {Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries},
  journal = {American Journal of Materials Synthesis and Processing},
  volume = {7},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajmsp.20220701.11},
  url = {https://doi.org/10.11648/j.ajmsp.20220701.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20220701.11},
  abstract = {This article explored the use of atomic layer deposition to deposit cathode material LF(M)S coated with nano-scale Al2O3(C) film by growth coating, and successfully obtained the composite LF(M)S coated with Al2O3 (C) cathode material. The test results of various electrochemical performance parameters show that the surface modification treatment method can effectively improve the various electrochemical properties of the cathode material. The synthesized LF(M)S was analyzed by a Time of Flight Secondary Ion Mass Spectrometer, and a clear topography and three-dimensional topography of the surface coated with Al2O3 and C were obtained; the surface morphology and uniformity of the deposited layer were studied by Atomic Force Microscope and the crystal structure of the material was analyzed by XRD. The electrochemical performance of the battery assembled with the positive electrode material was characterized by an electrochemical workstation and a charge-discharge tester. The results showed that the surface coating can effectively prevent the side reaction between the material and the electrolyte at high voltage, and reduce the irreversible capacity loss in the first charge and discharge process, because the chemical properties of the coating are not active. At the same time, due to the stable structure and good conductivity of the coating material, the stability of the structure during charging and discharging of the material is maintained, thereby reducing the loss of battery capacity, maintaining good conductivity between the material particles, and improving the cycle performance of the material.},
 year = {2022}
}

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TY  - JOUR
T1  - Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries
AU  - Wang Qingsheng
AU  - Povel Nivokov
AU  - Anadoli Popovich
AU  - Yu Yao
AU  - Yang Zhelong
Y1  - 2022/01/12
PY  - 2022
N1  - https://doi.org/10.11648/j.ajmsp.20220701.11
DO  - 10.11648/j.ajmsp.20220701.11
T2  - American Journal of Materials Synthesis and Processing
JF  - American Journal of Materials Synthesis and Processing
JO  - American Journal of Materials Synthesis and Processing
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2575-1530
UR  - https://doi.org/10.11648/j.ajmsp.20220701.11
AB  - This article explored the use of atomic layer deposition to deposit cathode material LF(M)S coated with nano-scale Al2O3(C) film by growth coating, and successfully obtained the composite LF(M)S coated with Al2O3 (C) cathode material. The test results of various electrochemical performance parameters show that the surface modification treatment method can effectively improve the various electrochemical properties of the cathode material. The synthesized LF(M)S was analyzed by a Time of Flight Secondary Ion Mass Spectrometer, and a clear topography and three-dimensional topography of the surface coated with Al2O3 and C were obtained; the surface morphology and uniformity of the deposited layer were studied by Atomic Force Microscope and the crystal structure of the material was analyzed by XRD. The electrochemical performance of the battery assembled with the positive electrode material was characterized by an electrochemical workstation and a charge-discharge tester. The results showed that the surface coating can effectively prevent the side reaction between the material and the electrolyte at high voltage, and reduce the irreversible capacity loss in the first charge and discharge process, because the chemical properties of the coating are not active. At the same time, due to the stable structure and good conductivity of the coating material, the stability of the structure during charging and discharging of the material is maintained, thereby reducing the loss of battery capacity, maintaining good conductivity between the material particles, and improving the cycle performance of the material.
VL  - 7
IS  - 1
ER  -

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Author Information

Wang Qingsheng

Technical Department, Zhejiang Changxing Sino-Russian New Energy Material and Technology Research Institute, Changxing, China
Povel Nivokov

Technical Department, Zhejiang Changxing Sino-Russian New Energy Material and Technology Research Institute, Changxing, China
Anadoli Popovich

Material Institute, Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia
Yu Yao

Technical Department, Zhejiang Changxing Sino-Russian New Energy Material and Technology Research Institute, Changxing, China
Yang Zhelong

Technical Department, Zhejiang Changxing Sino-Russian New Energy Material and Technology Research Institute, Changxing, China

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APA Style

Wang Qingsheng, Povel Nivokov, Anadoli Popovich, Yu Yao, Yang Zhelong. (2022). Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. American Journal of Materials Synthesis and Processing, 7(1), 1-7. https://doi.org/10.11648/j.ajmsp.20220701.11

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ACS Style

Wang Qingsheng; Povel Nivokov; Anadoli Popovich; Yu Yao; Yang Zhelong. Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. Am. J. Mater. Synth. Process. 2022, 7(1), 1-7. doi: 10.11648/j.ajmsp.20220701.11

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AMA Style

Wang Qingsheng, Povel Nivokov, Anadoli Popovich, Yu Yao, Yang Zhelong. Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries. Am J Mater Synth Process. 2022;7(1):1-7. doi: 10.11648/j.ajmsp.20220701.11

Copy | Download

@article{10.11648/j.ajmsp.20220701.11,
  author = {Wang Qingsheng and Povel Nivokov and Anadoli Popovich and Yu Yao and Yang Zhelong},
  title = {Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries},
  journal = {American Journal of Materials Synthesis and Processing},
  volume = {7},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajmsp.20220701.11},
  url = {https://doi.org/10.11648/j.ajmsp.20220701.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20220701.11},
  abstract = {This article explored the use of atomic layer deposition to deposit cathode material LF(M)S coated with nano-scale Al2O3(C) film by growth coating, and successfully obtained the composite LF(M)S coated with Al2O3 (C) cathode material. The test results of various electrochemical performance parameters show that the surface modification treatment method can effectively improve the various electrochemical properties of the cathode material. The synthesized LF(M)S was analyzed by a Time of Flight Secondary Ion Mass Spectrometer, and a clear topography and three-dimensional topography of the surface coated with Al2O3 and C were obtained; the surface morphology and uniformity of the deposited layer were studied by Atomic Force Microscope and the crystal structure of the material was analyzed by XRD. The electrochemical performance of the battery assembled with the positive electrode material was characterized by an electrochemical workstation and a charge-discharge tester. The results showed that the surface coating can effectively prevent the side reaction between the material and the electrolyte at high voltage, and reduce the irreversible capacity loss in the first charge and discharge process, because the chemical properties of the coating are not active. At the same time, due to the stable structure and good conductivity of the coating material, the stability of the structure during charging and discharging of the material is maintained, thereby reducing the loss of battery capacity, maintaining good conductivity between the material particles, and improving the cycle performance of the material.},
 year = {2022}
}

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TY  - JOUR
T1  - Influence of Atomic Deposition Surface Modification Technology on the Cycle Efficiency and Capacity of Lithium Ferrous Silicate Cathodes for Lithium-ion Batteries
AU  - Wang Qingsheng
AU  - Povel Nivokov
AU  - Anadoli Popovich
AU  - Yu Yao
AU  - Yang Zhelong
Y1  - 2022/01/12
PY  - 2022
N1  - https://doi.org/10.11648/j.ajmsp.20220701.11
DO  - 10.11648/j.ajmsp.20220701.11
T2  - American Journal of Materials Synthesis and Processing
JF  - American Journal of Materials Synthesis and Processing
JO  - American Journal of Materials Synthesis and Processing
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2575-1530
UR  - https://doi.org/10.11648/j.ajmsp.20220701.11
AB  - This article explored the use of atomic layer deposition to deposit cathode material LF(M)S coated with nano-scale Al2O3(C) film by growth coating, and successfully obtained the composite LF(M)S coated with Al2O3 (C) cathode material. The test results of various electrochemical performance parameters show that the surface modification treatment method can effectively improve the various electrochemical properties of the cathode material. The synthesized LF(M)S was analyzed by a Time of Flight Secondary Ion Mass Spectrometer, and a clear topography and three-dimensional topography of the surface coated with Al2O3 and C were obtained; the surface morphology and uniformity of the deposited layer were studied by Atomic Force Microscope and the crystal structure of the material was analyzed by XRD. The electrochemical performance of the battery assembled with the positive electrode material was characterized by an electrochemical workstation and a charge-discharge tester. The results showed that the surface coating can effectively prevent the side reaction between the material and the electrolyte at high voltage, and reduce the irreversible capacity loss in the first charge and discharge process, because the chemical properties of the coating are not active. At the same time, due to the stable structure and good conductivity of the coating material, the stability of the structure during charging and discharging of the material is maintained, thereby reducing the loss of battery capacity, maintaining good conductivity between the material particles, and improving the cycle performance of the material.
VL  - 7
IS  - 1
ER  -

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