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Quantification of Caffeine Concentration: An Electrochemical Method: A Review

Received: 27 November 2023    Accepted: 13 December 2023    Published: 26 December 2023
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Abstract

Caffeine is found in coffee bean and leaf, tea, coconut, soft drinks, different food items and pharmaceuticals. Concentration of caffeine found in different samples is not identical. Several conventional techniques have been developed for caffeine (CAF) determination. Due to their high sensitivity, selectivity, and low detection limit, chromatographic techniques such as liquid chromatography (LC), gas chromatography (GC), high performance liquid chromatography (HPLC,) and spectroscopic techniques such as mass spectroscopy (MS), near infrared ray spectroscopy (NIRs,) coupled with detectors such as photodiode array (PDA), detector, Refractive index (RI) detector, diode array detector (DA) All of these procedures, however, are sophisticated, time demanding, and need expensive equipment. In this aspect, the electrochemical technique overcomes those shortcomings due to its low cost, quick response, and use in on-site testing. It offers a number of advantages, including the fact that it requires little time, a little amount of chemicals, and does not yield complicated results. Recent breakthroughs in the electrochemical application of nanoparticle modified electrodes for caffeine detection in food, coffee bean, beverages, and medicinal formulations are discussed. As a result, the primary goal of this work is to discuss the advantages of adopting electro analytical methodologies over traditional methods for caffeine measurement using nanoparticle modified electrodes. For a multiple of advantages, electrochemical methods of caffeine quantifications are preferable.

Published in American Journal of Applied Chemistry (Volume 11, Issue 6)
DOI 10.11648/j.ajac.20231106.12
Page(s) 146-152
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Caffeine, Electrochemical Methods, Modified Electrodes, Nanoparticle

References
[1] Meredith, S. E., L. M. Juliano, J. R. Hughes, and R. R. Griffiths, Caffeine use disorder: a comprehensive review and research agenda. Journal of caffeine research, 2013. 3(3): 114-130.
[2] Habibi, B., M. Abazari, and M. H. Pournaghi-Azar, A carbon nanotube modified electrode for determination of caffeine by differential pulse voltammetry. Chinese Journal of Catalysis, 2012. 33(11-12): 1783-1790.
[3] Aly, A. A., M. A. Kassem, and A. S. Amin, Determination of caffeine in roasted and irradiated coffee beans with gamma rays by high performance liquid chromatography. Food Science and Quality Management, 2013. 22: 28-34.
[4] Chen, J., P. He, H. Bai, S. He, T. Zhang, X. Zhang, and F. Dong, Poly (β-cyclodextrin)/carbon quantum dots modified glassy carbon electrode: preparation, characterization and simultaneous electrochemical determination of dopamine, uric acid and tryptophan. Sensors and Actuators B: Chemical, 2017. 252: 9-16.
[5] Torres, A. C., M. M. Barsan, and C. M. Brett, Simple electrochemical sensor for caffeine based on carbon and Nafion-modified carbon electrodes. Food chemistry, 2014. 149: 215-220.
[6] Zou, J. and N. Li, Simple and environmental friendly procedure for the gas chromatographic–mass spectrometric determination of caffeine in beverages. Journal of Chromatography A, 2006. 1136(1): 106-110.
[7] Khorrami, A. R. and A. Rashidpur, Development of a fiber coating based on molecular sol–gel imprinting technology for selective solid-phase micro extraction of caffeine from human serum and determination by gas chromatography/mass spectrometry. Analytica chimica acta, 2012. 727: 20-25.
[8] Hadad, G. M., R. A. A. Salam, R. M. Soliman, and M. K. Mesbah, Rapid and simultaneous determination of antioxidant markers and caffeine in commercial teas and dietary supplements by HPLC-DAD. Talanta, 2012. 101: 38-44.
[9] Wang, H., L. Chen, Y. Xu, Q. Zeng, X. Zhang, Q. Zhao, and L. Ding, Dynamic microwave-assisted extraction coupled on-line with clean-up for determination of caffeine in tea. LWT-Food Science and Technology, 2011. 44(6): 1490-1495.
[10] Trani, A., R. Petrucci, G. Marrosu, D. Zane, and A. Curulli, Selective electrochemical determination of caffeine at a gold-chitosan nanocomposite sensor: May little change on nanocomposites synthesis affect selectivity? Journal of Electroanalytical Chemistry, 2017. 788: 99-106.
[11] Zhao, F., F. Wang, W. Zhao, J. Zhou, Y. Liu, L. Zou, and B. Ye, Voltammetric sensor for caffeine based on a glassy carbon electrode modified with Nafion and graphene oxide. Microchimica Acta, 2011. 174(3-4): 383-390.
[12] Santos, W. d. J. R., M. Santhiago, I. V. P. Yoshida, and L. T. Kubota, Electrochemical sensor based on imprinted sol–gel and nanomaterial for determination of caffeine. Sensors and Actuators B: Chemical, 2012. 166: 739-745.
[13] Khoo, W. Y. H., M. Pumera, and A. Bonanni, Graphene platforms for the detection of caffeine in real samples. Analytica chimica acta, 2013. 804: 92-97.
[14] Fekry, A., M. Shehata, S. Azab, and A. Walcarius, Voltammetric detection of caffeine in pharmacological and beverages samples based on simple nano-Co (II, III) oxide modified carbon paste electrode in aqueous and micellar media. Sensors and Actuators B: Chemical, 2020. 302: 127172.
[15] Mahanthappa, M., S. Yellappa, N. Kottam, and C. S. R. Vusa, Sensitive determination of caffeine by copper sulphide nanoparticles modified carbon paste electrode. Sensors and Actuators A: Physical, 2016. 248: 104-113.
[16] Santhosh, B., S. Manjunatha, M. Shivakumar, M. Dharmaprakash, and S. Manjappa, Electrochemical investigation of caffeine by cerium oxide nanoparticle modified carbon paste electrode. Journal of The Electrochemical Society, 2020. 167(4): 047503.
[17] Filik, H., A. A. Avan, S. Aydar, and G. Çetintaş, Determination of acetaminophen in the presence of ascorbic acid using a glassy carbon electrode modified with poly (caffeic acid). Int. J. Electrochem. Sci, 2014. 9: 148-160.
[18] Manikandan, V. S., B. Adhikari, and A. Chen, Nanomaterial based electrochemical sensors for the safety and quality control of food and beverages. Analyst, 2018. 143(19): 4537-4554.
[19] Bartlett, P. N., Bioelectrochemistry: fundamentals, experimental techniques and applications. 2008: John Wiley & Sons.
[20] Durst, R., Chemically modified electrodes: recommended terminology and definitions (IUPAC Recommendations 1997). Pure and applied chemistry, 1997. 69(6): 1317-1324.
[21] Hierlemann, A. and R. Gutierrez-Osuna, Higher-order chemical sensing. Chemical reviews, 2008. 108(2): 563-613.
[22] Suni, I. I., Impedance methods for electrochemical sensors using nanomaterials. TrAC Trends in Analytical Chemistry, 2008. 27(7): 604-611.
[23] Curulli, A., Nanomaterials in Electrochemical Sensing Area: Applications and Challenges in Food Analysis. Molecules, 2020. 25(23): 5759.
[24] Allen, J. B. and R. F. Larry, Electrochemical methods fundamentals and applications. 2001: John Wiley & Sons.
[25] Dincer, C., R. Bruch, E. Costa-Rama, M. T. Fernández-Abedul, A. Merkoçi, A. Manz, G. A. Urban, and F. Güder, Disposable sensors in diagnostics, food, and environmental monitoring. Advanced Materials, 2019. 31(30): 1806739.
[26] Porto, L. S., D. N. Silva, A. E. F. de Oliveira, A. C. Pereira, and K. B. Borges, Carbon nanomaterials: synthesis and applications to development of electrochemical sensors in determination of drugs and compounds of clinical interest. Reviews in Analytical Chemistry, 2020. 38(3).
[27] Bobrinetskiy, I. I. and N. Z. Knezevic, Graphene-based biosensors for on-site detection of contaminants in food. Analytical Methods, 2018. 10(42): 5061-5070.
[28] Kour, R., S. Arya, S.-J. Young, V. Gupta, P. Bandhoria, and A. Khosla, recent advances in carbon nanomaterials as electrochemical biosensors. Journal of The Electrochemical Society, 2020. 167(3): 037555.
[29] Hernandez-Aldave, S., A. Tarat, J. D. McGettrick, and P. Bertoncello, Voltammetric detection of caffeine in beverages at nafion/graphite nanoplatelets layer-by-layer films. Nanomaterials, 2019. 9(2): 221.
[30] Pumera, M., Graphene-based nanomaterials and their electrochemistry. Chemical Society Reviews, 2010. 39(11): 4146-4157.
[31] Xiao, T., J. Huang, D. Wang, T. Meng, and X. Yang, Au and Au-Based nanomaterials: Synthesis and recent progress in electrochemical sensor applications. Talanta, 2020. 206: 120210.
[32] Liu, Z., A. Nemec-Bakk, N. Khaper, and A. Chen, Sensitive electrochemical detection of nitric oxide release from cardiac and cancer cells via a hierarchical nanoporous gold microelectrode. Analytical chemistry, 2017. 89(15): 8036-8043.
[33] Masibi, K. K., O. E. Fayemi, A. S. Adekunle, E. S. M. Sherif, and E. E. Ebenso, Electrochemical Determination of Caffeine Using Bimetallic Au− Ag Nanoparticles Obtained from Low-cost Green Synthesis. Electroanalysis, 2020. 32(12): 2745-2755.
[34] Yang, G., F. Zhao, and B. Zeng, Facile fabrication of a novel anisotropic gold nanoparticle–chitosan–ionic liquid/graphene modified electrode for the determination of theophylline and caffeine. Talanta, 2014. 127: 116-122.
[35] Sun, J.-Y., K.-J. Huang, S.-Y. Wei, Z.-W. Wu, and F.-P. Ren, A graphene-based electrochemical sensor for sensitive determination of caffeine. Colloids and Surfaces B: Biointerfaces, 2011. 84(2): 421-426.
Cite This Article
  • APA Style

    Wale, K. (2023). Quantification of Caffeine Concentration: An Electrochemical Method: A Review. American Journal of Applied Chemistry, 11(6), 146-152. https://doi.org/10.11648/j.ajac.20231106.12

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    ACS Style

    Wale, K. Quantification of Caffeine Concentration: An Electrochemical Method: A Review. Am. J. Appl. Chem. 2023, 11(6), 146-152. doi: 10.11648/j.ajac.20231106.12

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    AMA Style

    Wale K. Quantification of Caffeine Concentration: An Electrochemical Method: A Review. Am J Appl Chem. 2023;11(6):146-152. doi: 10.11648/j.ajac.20231106.12

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  • @article{10.11648/j.ajac.20231106.12,
      author = {Kasahun Wale},
      title = {Quantification of Caffeine Concentration: An Electrochemical Method: A Review},
      journal = {American Journal of Applied Chemistry},
      volume = {11},
      number = {6},
      pages = {146-152},
      doi = {10.11648/j.ajac.20231106.12},
      url = {https://doi.org/10.11648/j.ajac.20231106.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20231106.12},
      abstract = {Caffeine is found in coffee bean and leaf, tea, coconut, soft drinks, different food items and pharmaceuticals. Concentration of caffeine found in different samples is not identical. Several conventional techniques have been developed for caffeine (CAF) determination. Due to their high sensitivity, selectivity, and low detection limit, chromatographic techniques such as liquid chromatography (LC), gas chromatography (GC), high performance liquid chromatography (HPLC,) and spectroscopic techniques such as mass spectroscopy (MS), near infrared ray spectroscopy (NIRs,) coupled with detectors such as photodiode array (PDA), detector, Refractive index (RI) detector, diode array detector (DA) All of these procedures, however, are sophisticated, time demanding, and need expensive equipment. In this aspect, the electrochemical technique overcomes those shortcomings due to its low cost, quick response, and use in on-site testing. It offers a number of advantages, including the fact that it requires little time, a little amount of chemicals, and does not yield complicated results. Recent breakthroughs in the electrochemical application of nanoparticle modified electrodes for caffeine detection in food, coffee bean, beverages, and medicinal formulations are discussed. As a result, the primary goal of this work is to discuss the advantages of adopting electro analytical methodologies over traditional methods for caffeine measurement using nanoparticle modified electrodes. For a multiple of advantages, electrochemical methods of caffeine quantifications are preferable.
    },
     year = {2023}
    }
    

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  • TY  - JOUR
    T1  - Quantification of Caffeine Concentration: An Electrochemical Method: A Review
    AU  - Kasahun Wale
    Y1  - 2023/12/26
    PY  - 2023
    N1  - https://doi.org/10.11648/j.ajac.20231106.12
    DO  - 10.11648/j.ajac.20231106.12
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 146
    EP  - 152
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20231106.12
    AB  - Caffeine is found in coffee bean and leaf, tea, coconut, soft drinks, different food items and pharmaceuticals. Concentration of caffeine found in different samples is not identical. Several conventional techniques have been developed for caffeine (CAF) determination. Due to their high sensitivity, selectivity, and low detection limit, chromatographic techniques such as liquid chromatography (LC), gas chromatography (GC), high performance liquid chromatography (HPLC,) and spectroscopic techniques such as mass spectroscopy (MS), near infrared ray spectroscopy (NIRs,) coupled with detectors such as photodiode array (PDA), detector, Refractive index (RI) detector, diode array detector (DA) All of these procedures, however, are sophisticated, time demanding, and need expensive equipment. In this aspect, the electrochemical technique overcomes those shortcomings due to its low cost, quick response, and use in on-site testing. It offers a number of advantages, including the fact that it requires little time, a little amount of chemicals, and does not yield complicated results. Recent breakthroughs in the electrochemical application of nanoparticle modified electrodes for caffeine detection in food, coffee bean, beverages, and medicinal formulations are discussed. As a result, the primary goal of this work is to discuss the advantages of adopting electro analytical methodologies over traditional methods for caffeine measurement using nanoparticle modified electrodes. For a multiple of advantages, electrochemical methods of caffeine quantifications are preferable.
    
    VL  - 11
    IS  - 6
    ER  - 

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Author Information
  • Jimma Agricultural Research Center, Ethiopian Institute of Agricultural Research, Jimma, Ethiopia

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